光纤基底TiNi形状记忆合金薄膜制备工艺

将TiNi基记忆合金薄膜与光纤相结合可制成智能化、集成化且成本经济的微机电系统和微传感器件.本文采用磁控溅射法在二氧化硅光纤基底上制备TiNi记忆合金薄膜,系统讨论了溅射工艺参数以及后续退火处理对薄膜质量的影响.采用自研制光纤镀膜掩膜装置在直径为125μm的光纤圆周表面上形成均匀薄膜.实验表明:在靶基距、背底真空度、Ar气流量和溅射时间一定的条件下,溅射功率存在最佳值;溅射压强较大时,薄膜沉积速率较低,但薄膜表面粗糙度较小.进行退火处理后,薄膜形成较良好的晶体结构,Ti_49.09Ni_50.91薄膜中马氏体B19′相和奥氏体B2相共存,但以B19′为主.根据本文研究结果,在玻璃光纤基底上制备高质量的TiNi基记忆合金薄膜是可实现的,本工作为下一步研制微机电系统和微型传感器做了基础准备.     

吉林大学物理化学学科:笃学致远 润物无声

伴随建系而生的吉林大学物理化学学科是吉大化学学科的重要组成部分,在70年的发展中为整个化学学科的发展建设做出了重要贡献。吉大物化人一直坚持理论与实践并重的教育思想,培养了大批优秀人才。回顾了吉大物理化学学科的历史沿革,展现了吉林大学化学学院物理化学在课程和教材建设、科学研究和人才培养等方面所取得的成绩。在吉大化学70周年华诞之际,谨以此文向为吉大物化学科建设做出贡献的前辈致敬。     

Freeze–Thaw-Promoted Fabrication of Clean and Hierarchically Structured Noble-Metal Aerogels for Electrocatalysis and Photoelectrocatalysis

Noble-metal aerogels (NMAs) have drawn increasing attention because of their self-supported conductive networks, high surface areas, and numerous optically/catalytically active sites, enabling their impressive performance in diverse fields. However, the fabrication methods suffer from tedious procedures, long preparation times, unavoidable impurities, and uncontrolled multiscale structures, discouraging their developments. By utilizing the self-healing properties of noble-metal aggregates, the freezing-promoted salting-out behavior, and the ice-templating effect, a freeze–thaw method is crafted that is capable of preparing various hierarchically structured noble-metal gels within one day without extra additives. In light of their cleanliness, the multi-scale structures, and combined catalytic/optical properties, the electrocatalytic and photoelectrocatalytic performance of NMAs are demonstrated, which surpasses that of commercial noble-metal catalysts.     

A Closed‐Loop Control Strategy for Producing Nitrile Rubber of Uniform Chemical Composition in a Semibatch Reactor: A Simulation Study

To improve the quality of industrial nitrile rubbers, the copolymer chemical composition, p_A(t), should ideally be kept constant along the reaction. This work proposes a closed‐loop control strategy for the semibatch operation of the reactor with the aim of regulating p_A(t) within a reduced range of variability. The proposed strategy is evaluated by simulating a mathematical model of the process. To this effect, a simplified mathematical model of the reaction is first derived and then utilized to obtain a suboptimal control law and a soft‐sensor that estimates the polymerization rates. The suboptimal control law is compensated by adding a term proportional to errors in p_A(t). The simulated example considers the production of the low‐composition AJLT grade, with the copolymerization reaction represented by a detailed mathematical model adjusted to an industrial plant. Due to the high performance of the soft‐sensor, the simulation results suggest that the proposed closed‐loop strategy is efficient to adequately regulate p_A(t) in spite of structural and parametric uncertainties, while other quality variables remained practically unaffected.     

Analyzing the coexistence of DSRC and Wi-Fi networks using the Poisson line Cox process

Vehicular networks can aid in traffic monitoring, autonomous driving, and car accidents prevention. Yet, the deployment of these networks has been delayed due to the limited spectrum, especially for the case of unlicensed operations. To handle this issue, the Federal Communications Commission (FCC) proposed to permit Wi-Fi devices to operate in the 5.9 GHz band allocated to the intelligent transportation system (ITS). In a recent work, we analyzed the impact of the coexistence of dedicated short range communications (DSRC) and Wi-Fi on future DSRC network deployments by developing a stochastic geometry analytical model that considers a dynamic medium access probability (MAP) of DSRC nodes which uses carrier sense multiple access with collision avoidance (CSMA/CA). This previous work was based on the standard 2D homogeneous Poisson Point Process (PPP) model. In this work, we model the roads using the more applicable but more complex Poisson line process (PLP) Cox point process. We generate performance metrics represented through coverage probability and area system throughput, and we compare these results to our earlier work. The importance of this work is two-fold. First, it allows a further understanding of the impact of DSRC-Wi-Fi coexistence on future DSRC network deployments, and second, it highlights the effectiveness of the PLP in modeling the distribution of vehicles in an area by producing more accurate performance results.     

Relationship of nanostructure and thermo-chemical response/thermal ablation of carbon aerogels

In this work, the interfacial mass balance relations combined with the non-parametric kinetic (NPK) analysis results were used for evaluating the thermo-chemical ablation process and oxidation mechanism of carbon aerogels with various porous structure. It was found that the two-parameter model of Nomen–Sempereis was able to describe the kinetics of the oxidation reaction and to reveal the structure-dependent contribution of two main processes with chemical and physical nature. The porosity of the carbon aerogel, rather than the other microstructural features, was realized more effective on the rate of ablation.     

ISSDE: A Monte Carlo implicit simulation code based on Stratonovich SDE approach of Coulomb collision

A Monte Carlo implicit simulation program, Implicit Stratonovich Stochastic Differential Equations(ISSDE), is developed for solving stochastic differential equations(SDEs) that describe plasmas with Coulomb collision. The basic idea of the program is the stochastic equivalence between the Fokker–Planck equation and the Stratonovich SDEs. The splitting method is used to increase the numerical stability of the algorithm for dynamics of charged particles with Coulomb collision. The cases of Lorentzian plasma, Maxwellian plasma and arbitrary distribution function of background plasma have been considered. The adoption of the implicit midpoint method guarantees exactly the energy conservation for the diffusion term and thus improves the numerical stability compared with conventional Runge–Kutta methods. ISSDE is built with C++ and has standard interfaces and extensible modules. The slowing down processes of electron beams in unmagnetized plasma and relaxation process in magnetized plasma are studied using the ISSDE, which shows its correctness and reliability.